The imbalance problem of talent structure in China, which is highlighted by “the most difficult employment” of undergraduates, have blocked Chinas economic development in a coordinated, stable and rapid way. With the analysis tool of “structural departure degree”, this paper testifies that the imbalance of the talent structure on the four dimensions of industry, region, business type and education background. To balance the talent structure and ease the difficult employment, the following adjustment strategies are proposed, such as restructuring the industrial structure, facilitating the marketization flow of regional talents, enhancing the absorptive function of private enterprises for talents and transforming the talent cultivating mode.